Illumination device

ABSTRACT

Embodiments of the invention include a semiconductor light emitting device for emitting a first light at a first wavelength and a wavelength conversion medium arranged to convert at least part of the first light into a second light at a second wavelength. The wavelength conversion medium is disposed between a periodic antenna array and the semiconductor light emitting device. The periodic antenna array includes a plurality of antennas. The periodic antenna array supports surface lattice resonances arising from diffractive coupling of localized surface plasmon resonances in at least one of the antennas.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a continuation of U.S. patent application Ser. No.14/853,419, filed Sep. 14, 2015, entitled “ILLUMINATION DEVICE, which isa continuation of U.S. patent application Ser. No. 13/995,998, filedJun. 20, 2013, issued as U.S. Pat. No. 9,157,605 on Oct. 13, 2015, whichis a 371(c) national stage entry of PCT/IB2012/050190 filed on Jan. 16,2012, which is the international application of EP 11151224.0 filed onJan. 18, 2011. U.S. patent application Ser. No. 14/853,419, U.S. patentapplication Ser. No. 13/995,998, International Application No.PCT/IB2012/050190, and EP 11151224.0 are incorporated herein byreference.

FIELD OF THE INVENTION

The invention relates to an illumination device. In particular itrelates to such a device applying a wavelength conversion medium. Such adevice is used in, for example, illumination systems, projectionsystems, and laser systems.

BACKGROUND OF THE INVENTION

An embodiment of an illumination device of the kind set forth is knownfrom U.S. Pat. No. 7,709,811. That document discloses an illuminationdevice comprising a blue LED (e.g. GaN or InGaN) light source, aninternal optical element, a wavelength converting material, and anexternal optical element (e.g. a plastic or glass lens). The wavelengthconverting material (e.g. an organic dye or inorganic phosphor) isapplied to a side of the internal element facing away from the LED. Theinternal optical element is a rectangular or pyramid shaped prism andserves to direct primary light emitted by the LED to the wavelengthconverting material. Moreover, it serves to redirect secondary lightemitted by the wavelength converting material in the backward direction(i.e. towards the LED) to a forward direction (i.e. away from the LED).The external optical element serves to define an application specificillumination distribution consisting of a mixture of the primary andsecondary light.

Devices as disclosed by U.S. Pat. No. 7,709,811 exhibit severaldifficulties limiting their usefulness, such as heat management issues,efficiency issues, and emission directionality issues.

For instance, many illumination applications prescribe LED based systemsproviding power levels on the order of a few Watts. When concentratinglight with such power levels in a relative small volume of phosphormaterial, the Stokes losses inherent to the wavelength conversionprocess result in high local heat dissipation. With a typicalconductivity of 0.1-10 WK-1 m-1 common to most phosphorous materials,heat transportation becomes a limiting factor at a typically appliedthickness (˜100 μm) of the phosphor layer necessary for realizingsufficient absorption of the exciting primary wavelength light. Thisresults in alleviated temperature levels of the phosphor which caneasily exceed 200-300° C. At such levels, the conversion efficiency ofthe phosphors drops significantly, potentially resulting in additionalpower losses and uncontrolled further heating.

Moreover, the overall efficiency of such illumination devices depends onthe efficiency of the excitation and emission processes in thewavelength converting material. The excitation efficiency depends on theabsorption strength of the phosphor at the primary wavelength lightemitted by the LED. The emission efficiency is influenced by both theextent to which the absorbed energy (i.e. primary wavelength light) isconverted into emitted energy (i.e. secondary wavelength light) and theextent to which this emitted energy is coupled out of the device in aforward direction. With respect to the absorption efficiency, manywavelength converting materials exhibit a relative low absorptioncoefficient (typically 10-100 cm-1 upon excitation in the 400-480 nmrange). This implies that a 100-1000 μm thick layer of wavelengthconverting material is required for sufficient, or even complete,absorption of the excitation radiation. Such relatively largethicknesses may lead to an extended size of the light emitting area,especially when used in combination with laser light sources, and thusto a limited use of such devices as low étendue light sources in f.i.projection applications as beamers or car head lights.

Furthermore, a flat emission surface of the wavelength convertingmaterial gives rise to a Lambertian emission profile. While beam shapingoptical elements are known to be useful to realize the applicationspecific illumination distribution, these optical elements are usuallybulky, need precise alignment with the LED and/or wavelength convertingmaterial, and are typically based on weakly dispersing materials (e.g.glass, plastics) which do not allow different beam shaping and beamdirecting of different light colors.

SUMMARY OF THE INVENTION

The invention has as an objective providing an illumination device ofthe kind set forth in which at least one of the problems mentioned aboveis alleviated. This objective is achieved with an illumination device,designed to provide an application specific illumination distribution,comprising:

(i) a light source arranged to emit light at a primary wavelength,

(ii) a wavelength conversion medium arranged in light receivingrelationship with the light source and designed to convert at least partof the primary wavelength light into secondary wavelength light, and

(iii) a periodic antenna array disposed in close proximity to thewavelength conversion medium and arranged such that the antenna arraysupports surface lattice resonances arising from diffractive coupling oflocalized surface plasmon resonances in individual antennas for enablingthe application specific illumination distribution. Advantageously, theinvention provides an illumination device that allows the use of athinner wavelength conversion medium, because the efficiency of thewavelength conversion processes (excitation and/or emission) areenhanced. Moreover, the device allows through appropriate design of theperiodic antenna array to control the color, the directionality, and thepolarization, as well as allows increasing the intensity, of the lightemitted.

The term “close proximity” as used herein refers to a distance betweenthe periodic antenna array and the wavelength conversion medium that issmaller than about the wavelength of the primary and/or secondary light.For typical illumination devices this distance thus should be smallerthan 700 nm, preferably smaller than 300 nm, even more preferablesmaller than 100 nm. Close proximity therefore also includes thesituation where the antenna array is applied on a surface of thewavelength conversion medium. It also includes the situation where theantenna array is encompassed by the wavelength conversion medium.

An embodiment of the invention according to claim 2 provides theadvantage of improving the wavelength conversion process through thecoupling of the incident primary wavelength light or the emittedsecondary light to the surface lattice resonances that arise from thediffractive coupling of localized surface plasmon polaritons in theindividual antennas of the array.

According to an embodiment of the invention, the periodicity of theantenna array is of the order of the primary or secondary wavelengthlight. Beneficially, this allows the light to excite surface latticeresonances.

The embodiment of the illumination device according to claim 4beneficially allows controlling the modification of the illuminationdistribution of the device. This modification of the emitted lightdistribution from Lambertian to a more confined solid angle isespecially interesting for low etendue lighting applications such asprojection in beamers and automotive front lighting.

The embodiment of the invention of claim 5 advantageously allows for abetter coupling of the primary and/or secondary wavelength light withthe antennas and surface lattice resonances of the array.

In an embodiment according to claim 6, the stretchably controllablesubstrate allows active control of the emission efficiency, thedirectionality of the emission, and the emitted wavelength of theillumination device.

In embodiments according to claims 7 to 10, the two sub-arrays allow forappropriately designing the antenna array to accommodate several opticalphenomena, such as, for instance, one sub-array enhances the excitationof the wavelength conversion medium, while the other sub-array enhancesthe emission of and defines the direction of the secondary wavelengthlight.

The embodiments of claims 11 to 14 advantageously allow designing adistributed feedback light emitting device, such as a distributedfeedback laser.

These and other aspects of the invention will be apparent from andelucidated with reference to the embodiments described hereinafter.Appreciate, however, that these embodiments may not be construed aslimiting the scope of protection for the invention.

BRIEF DESCRIPTION OF THE DRAWINGS

Further details, features and advantages of the invention are disclosedin the following description of exemplary and preferred embodiments inconnection with the drawings.

FIG. 1 schematically shows an illumination device in accordance with anembodiment of the invention.

FIG. 2A shows diagrammatically a periodic antenna array.

FIG. 2B shows the transmittance through the antenna array of FIG. 2A asa function of the wave vector parallel to the plane of the array and thefrequency.

FIG. 3 shows schematically the effect of an adjustment of the antennaarray parameters on the emission characteristics of an illuminationdevice.

FIG. 4 shows schematically an embodiment of an antenna array.

FIG. 5 schematically shows an illumination device in accordance with anembodiment of the invention.

FIG. 6A shows the extinction of light through the antenna array of anembodiment of FIG. 5 as a function of the wave vector parallel to theplane of the array and the light frequency.

FIG. 6B shows the extinction of light through the antenna array ofanother embodiment of FIG. 5 as a function of the light frequency andantenna length for light incident at an angle of ˜1.2°.

FIG. 7A schematically shows part of an illumination device exhibiting awaveguide structure in accordance with an embodiment of the invention.

FIG. 7B shows the extinction of light through the waveguide structure ofFIG. 7A.

DETAILED DESCRIPTION OF THE EMBODIMENTS

FIG. 1 shows an illumination device 100 in accordance with theinvention. The illumination device 100 comprises a light source 110, forinstance a semiconductor light source such as a (inorganic or organic)light emitting diode (LED), a resonant cavity light emitting diode, alaser diode (LD), such as a vertical cavity laser diode or an edgeemitting laser diode. Material systems currently of interest in themanufacture of such semiconductor light sources capable of operating inthe visible spectrum include Group III-V semiconductors. In particularbinary, ternary, and quaternary alloys of gallium, aluminium, indium,and nitrogen, also referred to as III-nitride materials, are ofinterest. Typically, III-nitride semiconductor light sources arefabricated by epitaxially growing a stack of semiconductor layers ofdifferent composition and dopant concentrations on a sapphire, siliconcarbide, III-nitride, or other suitable substrate by metal-organicchemical vapour deposition, molecular beam epitaxy, or other epitaxialtechniques. The stack often includes (i) one or more n-type layers dopedwith, for example, Si, formed over the substrate, (ii) a light emittingor active region formed over the n-type layer or layers, and (iii) oneor more p-type layers doped with, for example, Mg, formed over theactive region. Often III-nitride semiconductor light sources arefabricated on insulating substrates, such as sapphire, with bothcontacts on the same side of the device. Such light sources are mountedso light is extracted either through the contacts (known as anepitaxy-up device) or through a surface of the light source opposite thecontacts (known as a flip-chip device). Light source 110 is arranged toemit a primary wavelength light 111. Depending on the alloy applied inthe semiconductor light sources discussed above, the primary wavelengthlight ranges from the near UV (˜365 nm) to the near IR (˜1000 nm).

Furthermore, illumination device 100 comprises a wavelength conversionmedium 120. The wavelength conversion medium may for instance comprise aphosphor, quantum dots, organic fluorescent dye molecules, etc. Theprimary wavelength light 111 emitted by the light source 110 is at leastin part converted into secondary wavelength light 122 by the wavelengthconversion medium 120. For many practical wavelength conversion mediaknown in the art, the primary wavelength light emitted by semiconductordevices matching the excitation spectrum of these media ranges from ˜400nm to ˜490 nm

In accordance with an embodiment a wavelength conversion medium 120comprising a phosphor is formed into a ceramic slab, referred to hereinas “luminescent ceramic.” Such ceramic slabs are generallyself-supporting layers formed separately from the light source 110.Subsequently they are attached to the finished (semiconductor) lightsource or positioned in light receiving relationship to the lightsource. The ceramic layer may be translucent or transparent. In thelatter case, scattering losses associated with non-transparentwavelength conversion media may be considerably reduced. In addition,since luminescent ceramic layers are solid, it may be easier to makeoptical contact with additional optical elements, such as an antennaarray 300. Examples of phosphors that may be formed into luminescentceramic layers include aluminum garnet phosphors with the generalformula (Lu_(1-x-y-a-b)Y_(x)Gd_(y))₃(Al_(1-z)Ga_(z))₅O₁₂:Ce_(a)Pr_(b)wherein 0<x<1, 0<y<1, 0<z≦0.1, 0<a≦0.2 and 0<b≦0.1, such asLu₃Al₅O₁₂:Ce³⁺ and Y₃Al₅O₁₂:Ce³⁺ which emit light in the yellow-greenrange; and(Sr_(1-x-y)Ba_(x)Ca_(y))_(2-z)Si_(5-g)Al_(a)N_(8-a)O_(a):Eu_(z) ²⁺wherein 0≦a<5, 0<x≦1, 0≦y≦1, and 0<z ≦1 such as Sr₂Si₅N₈:Eu²⁺, whichemit light in the red range. Suitable Y₃Al₅O₁₂:Ce³⁺ ceramic slabs may bepurchased from Baikowski International Corporation of Charlotte, N.C.Other green, yellow, and red emitting phosphors may also be suitable,including (Sr_(1-a-b)Ca_(b)Ba_(c))Si_(x)N_(y)O_(z):Eu_(a) ²⁺(a=0.002−0.2, b=0.0−0.25, c=0.0−0.25, x=1.5−2.5, y=1.5−2.5, z=1.5−2.5)including, for example, SrSi₂N₂O₂:Eu²⁺;(Sr_(1-u-v-x)Mg_(u)Ca_(v)Ba_(x))(Ga_(2-y-z)Al_(y)In_(z)S₄):Eu²⁺including, for example, SrGa₂S₄:Eu²⁺; Sr_(1-x)Ba_(x)SiO₄:Eu²⁺; and(Ca_(1-x)Sr_(x))S:Eu²⁺ wherein 0<x≦1 including, for example, CaS:Eu²⁺and SrS:Eu²⁺.

In accordance with an embodiment wavelength conversion medium 120 maycomprise quantum dots. These quantum dots may comprise CdS, CdSe, CdTe,ZnS, or ZnSe and may optionally be overcoated with a material comprisingZnS, ZnSe, CdS, CdSe, CdTe, or MgSe. The quantum dots may be furthercoated with a material having an affinity for a host matrix in whichthey are embedded, such as a monomer related to a polymer component ofthe host matrix. Advantageously, such a coating enables the quantum dotsto be dispersed in the host matrix without flocculation. The host matrixmay be a polymer such as polystyrene, polyimide, or epoxy, a silicaglass, or a silica gel.

In accordance with an embodiment wavelength conversion medium 120 maycomprise organic fluorescent molecules dissolved in a host matrix. Forexample, BASF Lumogen dyes in host materials like Polymethylmethacrylaat(PMMA), Polycarbonate (PC), Polyethylene terephthalate (PET),Polyethylene naphthalate (PEN).

The illumination device 100, moreover, comprises a periodic antennaarray 300 which is disposed in close proximity to the wavelengthconversion medium 120, i.e. a distance between the periodic antennaarray and the wavelength conversion medium is smaller than about thewavelength of the primary and/or secondary light. The array may bedisposed on a side of the wavelength conversion medium 120 facingtowards the light source 110, such as indicated in FIG. 1.Alternatively, the periodic antenna array 300 may be positioned on aside of the wavelength conversion medium facing away from the lightsource. The periodic antenna array 300 is formed by antennas 301 (seeFIG. 2A) comprising a highly polarisable material, for instance, ametal. As an example, antennas may comprise noble metals such as gold,silver, copper, platinum, and palladium. Alternatively, they maycomprise metals such as nickel, or aluminium. Alloys of the metalsmentioned are also possible. Alternatively, the antennas 301 may consistof two metal layers: a thin lower one for adhesive purposes such aschromium, and a thicker upper one comprising a metal or alloy describedabove.

Thus, in an embodiment the periodic antenna array may be deposited on a(transparent) substrate 140, such as quartz, sapphire, or an un-dopedceramic slab using f.i. substrate conformal imprint lithography. Thistechnique uses a stamp composed of two rubber layers on a thin glasssubstrate. The patterns are moulded in a stiff silicone rubber, and thethin glass plate is flexible in the out-of-plane direction. Thisflexibility allows for conformal contact to be made, thereby renderingaccurate reproduction of nano-scale features over a very large surfacearea despite possible presence of defects or surface contamination.Arrays as large in size as 12 inch wafers comprising antennas withtypical sizes of 250×40 nm² and with periodicities in the 200-600 nmrange can be easily made with this technique. A wavelength conversionmedium 120 comprising quantum dots (with or without an appropriate hostmatrix) may for instance be spin-coated over the antenna array 300.Alternatively, organic fluorescent molecules in an appropriate hostmatrix may be spin coated over the antenna array. As it is advantageousthat the antennas are embedded in an optically homogeneous medium,preferably the host matrix/wavelength conversion medium has the same, orsubstantially similar, effective index of refraction as the substrate140. Such a uniform optical surrounding environment allows for a bettercoupling of the primary and/or secondary wavelength light with theantennas and surface lattice resonances of the array, since thescattered light in the wavelength conversion medium 120 can thenpropagate in phase with that in the substrate 140. Substantially similareffective index of refraction at the wavelength of the surface latticeresonance in this context means that An is smaller than 0.5, preferablysmaller than 0.3, more preferably smaller than 0.05. In general, smallerantennas 301 require a more symmetric environment. Alternatively, whenthe periodic antenna array 300 is deposited on an un-doped ceramic slab,this slab may be bonded to a doped ceramic slab forming the wavelengthconversion medium 120. Arranging the periodic antenna array 300sandwiched between doped and un-doped ceramic slabs comprising the samehost crystal is especially advantageously, as these slabs have the sameindex of refraction. The space between the two slabs and the antennaarray may be filled with a material (such as a fluid, polymer, orsolgel) having an index of refraction matching the index of refractionof the two slabs to further enhance the optical uniformity of thearray's environment.

Alternatively still, the antenna array 300 may be sandwiched between twowavelength conversion media 120. For instance, the antenna array 300 maybe disposed on a first wavelength conversion medium 120, while a secondwavelength conversion medium covers the antenna array. In an embodimentthe first and second wavelength conversion media are formed by two dopedceramic slabs. In another embodiment, the first wavelength conversionmedium is formed by a doped ceramic slab on which the antenna array isdeposited, and the second comprises quantum dots spin coated over thearray. In these embodiments the wavelength conversion medium 120encompasses the antenna array 300. Optionally, the wavelength conversionmedium 120 may comprise two (or more, such as three or four) materialshaving distinct emission spectra or colors. Such a plurality ofmaterials may form a substantially homogeneous wavelength conversionmedium. Alternatively, the materials may be physically separated, suchas in the sandwiched embodiment described above.

The periodic antenna array 300 is arranged such that it supports surfacelattice resonances arising from diffractive coupling of localizedsurface plasmon resonances in individual antennas 301. Localized surfaceplasmon resonances are non-propagating surface modes excited via thecoupling of conducting electrons in the antennas 301 with anelectromagnetic field, such as the primary wavelength light 111 and/orthe secondary wavelength light 122. The electromagnetic field drives theconducting electrons to oscillate inside an antenna 301, resulting in adipolar or multi-polar field emanating from the antenna in dependence oftheir form factor. Moreover, charge accumulation of the driven electronsat the surface of the antenna will lead to a depolarization field insidethe antenna. The localized surface plasmon resonance takes place whenthe response of the electrons shows a π/2 phase lag with respect to thedriving electromagnetic field. The spectral position (i.e. frequency orwavelength at which the resonance occurs) and the features of theresonance are determined by the material composition, size, geometry,and surrounding environment of the antennas 301. Moreover, they aredetermined by the polarization of the electromagnetic field and byinter-antenna coupling. By appropriately controlling these parameters,the primary wavelength light 111 may be resonant with the localizedsurface plasmon resonances, allowing an enhancement of the excitation ofthe wavelength conversion medium 120. Advantageously, the inventionprovides an illumination device 100 that allows the use of a thinnerwavelength conversion medium 120, because the efficiency of thewavelength conversion process is enhanced. Moreover, the thinnerwavelength conversion medium 120 functioning as a secondary light sourceimproves the suitability of the illumination device 100 as a low etenduelight emitting device, especially when using a laser (diode) as a lightsource 110. Furthermore, the localized surface plasmon resonances can beexcited for any angle of incidence of the primary wavelength light 111to the plane of the antenna array 300, advantageously allowing the useof a non-collimated LED.

The excitation efficiency can be further enhanced by coupling theincident primary wavelength light 111 to surface lattice resonances thatarise from diffractive coupling of individual localized surface plasmonresonances. Advantageously, the primary wavelength light 111 can becollimated to optimize the coupling to surface lattice resonances.Therefore, the illumination device 100 may comprise an optionalcollimating optic 160, such as a lens or a compound parabolic collimator(see FIG. 1). In addition, the illumination device may comprise anoptional polariser (f.i. integrated with the collimating optic 160) tocontrol the polarization of the primary wavelength light 111 relative tothe orientation of the antennas 301. Further to, or instead of,enhancing the excitation efficiency through coupling of the primarywavelength light 111 to the surface lattice resonances of the periodicantenna array 300, the secondary wavelength light 122 may couple to suchlattice resonances. Due to this coupling the secondary wavelength light122 may be emitted from the illumination device 100 within a predefinedsolid angle Ω at a predefined angle a relative to the optical axis 200of the device. In contrast, absent the periodic antenna array 300 thesecondary light will essentially be emitted from the wavelengthconversion medium 120 with a Lambertian distribution. This modificationof the emitted light distribution from Lambertian to a more confinedsolid angle is especially interesting for low etendue lightingapplications such as projection in beamers and automotive frontlighting. Thus, the application of the periodic antenna array 300according to an embodiment of the invention effectively enhances theuseful emission of the illumination device 100 in such applications byincreasing the decay of the excited wavelength conversion medium 120into lattice modes grazing to the antenna array 300 and by couplingthese modes to free space radiation through scattering in the array.This enhancement may reach a factor of 10, 20, or even more than 50within a certain wavelength-angle region compared to the Lambertianemission profile obtained without the application of the antenna array.

The two effects described above—pump enhancement and emissionmodification—can be combined or applied independently, depending on thegeometry and dimensions of the antennas 301 and their spatialconfiguration in the array 300. Thus, as the strength of the couplingdepends on the wavelength and the polarization, and the directionalityof the emission of secondary wavelength light 122 closely resembles theangular dispersion of the surface lattice resonances, an applicationspecific illumination distribution—including the color (hue, saturation,color point, color temperature), the direction, and the polarization—canbe realized by designing the periodic antenna array 300 appropriately.

Surface lattice resonances can effectively be excited when the antennas301 are periodically arranged in the array 300 with a lattice constantcoextensive with the wavelength of the scattered (primary and/orsecondary) light. The resonances result from a partial cancelation ofthe damping associated with the localized surface plasmon resonance ofsingle antennas 301 by the retarded field coherently scattered by thearray 300. Surface lattice resonances occur near (usually a bitred-shifted to) the energy where a diffraction order changes fromradiating to evanescent in character, i.e. near a Rayleigh anomaly. Thewavelength at which the Rayleigh anomaly occurs is mainly determined bythe lattice constants and the refractive index of the medium surroundingthe antenna array 300. For a wave vector component parallel to the planeor the array 300 given by k_(//)=2π/λ sin(θ_(in))ŷ, it is the solutionto the equation

$k_{out}^{2} = {{k_{in}^{2}{\sin^{2}\left( \theta_{in} \right)}} + {m_{1}^{2}\left( \frac{2\pi}{a_{x}} \right)}^{2} + {m_{2}^{2}\left( \frac{2\pi}{a_{y}} \right)}^{2} + {2k_{in}{\sin \left( \theta_{in} \right)}{{m_{2}\left( \frac{2\pi}{a_{y}} \right)}.}}}$

Here, (m₁,m₂) are integers defining the diffraction order, and k_(out)and k_(in) are the scattered and incident wave vectors, respectively.The angle of incidence of the light relative to the normal to the planeof the antenna array 300 is denoted by θ_(in) (assuming φ_(in)=0—seeFIG. 2A), and a_(x) and a_(y) define the periodicities of the array inthe respective directions.

As indicated in FIG. 2A, the antennas 301 may have a rectangular formfactor with a length L, a width W, and a height H, and positioned in arectangular array with periodicities a_(x) and a_(y). L may range from50 nm to 400 nm, W may range from 20 nm to 200 nm, and H may range from10 nm to 70 nm. The periodicity a_(x) of the array 300 typically rangesfrom 150 nm to 600 nm or ˜1.5×L to ˜2×L, while the periodicity a_(y)typically ranges from 100 nm to 300 nm or ˜1.5×W to ˜3×W. As an example,an array 300 of antennas 301 comprising silver with dimensionsL×W×H=250×70×20 nm³ configured in a rectangular lattice with constantsa_(x)=350 nm and a_(y)=200 nm deposited on a quartz substrate andcovered with a 200 nm thick coating of CdSe/CdS core shell quantum dots,yields a localized surface plasmon resonance for light with apolarization parallel to the short axis of the antennas at 484 nm[ω/c=2π/λ], and a surface lattice resonance near 587 nm (see FIG. 2B).The figure depicts (relative scale on the right hand side) thetransmittance of light through the array/quantum dot structure. As canbe observed, the localized surface plasmon resonance at around 484 nmremains nearly constant for all values of k_(//) (again: φ_(in)=0),indicating their non-propagating or localized behavior. This alsoindicates that this resonance can be excited by light with essentiallyany angle of incidence enabling enhanced absorption of the primarywavelength light 111 from a non-collimated light source 110. Thediffractive coupling of the localized surface plasmon resonances leadsto an optically much narrower reduction in the light transmitted around587 nm at k_(//)=0, i.e. at normal incidence. The diffractive couplingin this case takes place along the direction perpendicular to thepolarization, i.e. along the x-direction. The position of the Rayleighanomalies is indicated by the black curve.

The antennas 301 do not necessarily have to be rectangular: they may bechosen from the group consisting of circular, elliptical, andpolygonal—such as triangular, square, rectangular, pentagonal, andhexagonal—shapes. Also the periodicity of the array 300 may be chosenfrom the group consisting of a square array, a rectangular array, atriangular array, a hexagonal array, and a quasi-crystal array.Quasi-crystals constitute a class of arrays having forbidden crystalsymmetry, such as 5-fold or 10-fold symmetry. Both the shape of theindividual antennas 301 and the periodicity of the array 300 influencethe symmetry and direction of the light emitted by the illuminationdevice 100. For instance, more circular shapes and a squarer periodicityresult in an illumination distribution with a more symmetricalcharacter. Alternatively, antennas with an asymmetrical shape, such astriangular or substantially triangular (pear like) shapes result in anasymmetrical illumination distribution. The later may be beneficial inlighting application requiring such an asymmetrical light distribution,such as the dipped or passing beam in automotive front lighting.

As an example, a donut or ring type illumination distribution ispossible through application of two or more antenna arrays 300. Forinstance, two or more arrays with a rectangular lattice may be orientedsuch that the long axis of the antennas 301 in one array is rotated withrespect to another array. Consider for example the case of two identicalarrays with mirror symmetry rotated with respect to each other by 90degrees. If the arrays sustain surface lattice resonances along onedirection only and overlapping the emission of the phosphor at largeangles only, the emission will be enhanced by the antennas 301 at largeangles only. One array will therefore enhance the emission towards the+/−x-direction, whereas the other array will enhance the emissiontowards the +/−y-direction, in both cases at large angles only. Byfurther adding arrays that are rotated with respect to each other asmentioned above, a donut shaped beam may be created. These arrays may belocated in one plane, so that they essentially can be construed asinterwoven sub-arrays forming a super-array. Alternatively, the arraysmay be positioned in a stacked configuration, in which a first antennaarray may be in close proximity to a side of the wavelength conversionmedium 120 facing towards the light source 110, and a second antennaarray may be in close proximity to a side facing away from the lightsource. In an embodiment, such a stacked configuration may comprisemultiple antenna arrays and wavelength conversion media alternating eachother, such as three antenna arrays and two wavelength conversion mediain the configuration array1-medium1-array2-medium2-array3. Such astacked configuration can be extended with more arrays and media,wherein each of these arrays may be comprise different antennamaterials, may comprise sub-arrays, or may have different periodicities,and wherein the wavelength conversion media may all comprise a singlematerial, may each comprise different materials, or may comprise amixture of wavelength conversion materials.

FIG. 3 qualitatively explains the influence of the design of the antennaarray 300 on the emission characteristics of illumination device 100,assuming array 300 is designed to support surface lattice resonances atthe secondary wavelength light 122. Depicted is the optical spectrum onthe vertical axis versus the appropriate wave vector parallel to theplane of the array. Curve 400 depicts the spectral intensity of theemission spectrum of the wavelength conversion medium 120. Curves 410and 420 depict the dispersion relation of surface lattice resonances ofa first array and a second array, respectively. In general, smaller formfactor antennas and lower periodicities of an array shift thecorresponding localized surface plasmon resonances and surface latticeresonances, respectively, to the blue part of the spectrum. Also, theresonances of silver antennas are blue shifted relative to gold antennaswith the same geometrical characteristics and periodicities. Thus, forinstance in the configuration shown, the first array (curve 410) isdenser than the second array (curve 420). Optical enhancement occurswhere curves 410 and 420 overlap (thick line segments) with the emissionspectrum 400 of the phosphor. Due to the smaller overlap of curves 420and 400, the emission of illumination device 100 may have a moresaturated color when applying the second array. Also, advantageously,the light will be emitted at a larger angles α2 relative to the normalof the plane of the array 300, compared to the smaller angles α1 whenapplying the first array. Assuming the array is positioned normal to theoptical axis 200 of the illumination device, these angles correspond tothe emission angle α (see FIG. 1). The array, however, does necessarilyhave to be positioned normal to the optical axis.

In an embodiment, the periodic antenna array 300 is positioned on a sideof the wavelength conversion medium 120 facing towards the light source110. Such a configuration is, for instance, especially beneficial incase the wavelength conversion medium has a thickness which extendsbeyond the interaction length with the array, i.e. a thickness largerthan about the wavelength of the primary and/or secondary light. Thewavelength conversion device 120 can then be thought of to comprise of afirst part and a second part. The first part, in close proximity withthe antenna array 300, will show emission characteristics determined bythe interaction with the array (radiation enhancement, modified emissiondistribution, etc), as described above. The second part will show a“classical” emission characteristic in which the secondary wavelengthlight is emitted over 4π, i.e. both in the forward and in the backwarddirection, i.e. towards light source 110. The light emitted in thebackward direction may now interact with the array 300 through a surfacelattice resonance. Part of this backward directed light may be reflectedby the antenna array, thereby enhancing the emission efficiency of thedevice by reducing the loss of secondary wavelength light 122 in thebackward direction.

In an embodiment, the periodic antenna array 300 comprises twointerwoven sub-arrays (FIG. 4). The first sub-array 310 comprises firstantennas 311, and the second sub-array 320 comprises second antennas322. Each sub-array may have its own periodicity and the form factor andmaterial composition of the antennas of each sub-array may be chosenappropriately to tune for a desired optical effect. For instance, thefirst antennas may comprise gold and have a rectangular shape, while thesecond antennas may comprise silver and have a substantially triangularshape. Alternatively to a triangular shape of an antenna in the plane ofthe array as depicted in FIG. 4, the triangular shape may be out ofplane, as f.i. formed by a pyramid, a ridge, or a tetrahedron shapedantenna. Advantageously, the second sub-array 320 may be designed suchthat the primary wavelength light 111 excites the localized surfaceplasmon resonances to enhance the excitation of the wavelengthconversion material 120, while the first sub-array 310 may be designedto support surface lattice resonances at the secondary wavelength light122, i.e. within the emission spectrum of the wavelength conversionmedium 120. Alternatively, the wavelength conversion medium 120 maycomprise two materials, such as two phosphors or two types of quantumdots, having a first emission wavelength range and a second emissionwavelength range, respectively. Periodic antenna array 300 may now bedesigned such that the first sub-array 310 supports surface latticeresonances arising from diffractive coupling of localized surfaceplasmon resonances in the individual first antennas 311 at a secondarywavelength 122 within the first emission wavelength range. Moreover, thesecond sub-array 320 may support surface lattice resonances arising fromdiffractive coupling of localized surface plasmon resonances in theindividual second antennas 322 at a secondary wavelength 122 within thesecond emission wavelength range. This allows controlling the emissioncharacteristics of the illumination device 100 in both direction andcolor. The application specific illumination distribution may compriselight with a first color point or color temperature emitted in a firstsolid angle Ω1 and a first angle α1 relative to the optical axis 200 ofthe illumination device 100, and light with a second color point orcolor temperature emitted in a second solid angle Ω2 and a second angleα2. As an example, the low or dipped beam of a vehicle may beneficiallycomprise light with a more yellowish color point towards the middle ofthe road and light with a more bluish color point towards the road side.Advantageously, such a light distribution will reduce discomfort toupcoming drivers, while simultaneously allows the car driver a betterview—since the human eye is more sensitive in the blue part of thevisible spectrum under scotopic light conditions—of signs or persons atthe road side/pavement.

In an embodiment, the substrate 140 is arranged to be stretchablycontrollable. As an example, an optically transparent material showing apiezo-electrical effect, such as litium niobate (LiNbO₃) or potassiumtitanyl phosphate (KTP), may function for forming the substrate 140. Theelectrically controllable expansion and contraction of such materialsallows adjusting the periodicity of the antenna array 300, either in asingle (x or y) direction or in both directions. As the opticalfrequency at which the surface lattice resonance occurs is determinedamongst others by the periodicity of the array, this allows activecontrol of the emission efficiency, the directionality of the emission,and the emitted wavelength of illumination device 100. Alternatively,the antenna array 300 may be deposited on a deformable polymer substrate140, such as a substrate comprising polydimethylsiloxane (PDMS) that canbe stretched mechanically to over 30%. The mechanical stretching mightbe electrically controllable through the use of a microelectromechanicalsystem (MEMS), or might be thermal or humidity induced. In anotherembodiment, the antenna array 300 may be deposited on a substratecomprising liquid crystalline polymers that deform subject to a phasetransition. The latter may be electrically controllable.

In an embodiment of the invention in accordance with FIG. 5, theillumination device 500 is designed to provide an application specificillumination distribution, and comprises a light source 510 arranged toemit light at a primary wavelength 511, a wavelength conversion medium520 arranged in light receiving relationship with the light source anddesigned to convert at least part of the primary wavelength light intosecondary wavelength light 522, and a periodic antenna array 530disposed in close proximity to the wavelength conversion medium andarranged such that the antenna array supports a frequency gap within theemission spectrum of the wavelength conversion medium, for instance atthe peak wavelength of the emission spectrum or at a wavelength in theflank of the emission spectrum. In another embodiment, the antenna array530 supports an electromagnetically induced transparency within theemission spectrum at the secondary wavelength light 522 emitted from theillumination device 500. In yet another embodiment, the antenna array530 supports both a frequency gap and an electromagnetically inducedtransparency.

FIG. 6A shows the extinction of an 3×3 mm² array 530 of gold antennaswith dimensions 450×120×38 nm³ arranged in a lattice with constantsa_(x)=600 nm and a_(y)=300 nm positioned on a glass substrate (see insetSEM image) The extinction spectrum is displayed as a function of thereduced frequency w/c and the projection of the incident wave vectoronto the plane of the array. The polarization of the light was set alongthe y-direction, probing the short axis of the antennas. The extinctiondisplays a number of resonances. First of all, the broad anddispersionless peak centered at ˜9 mrad/nm corresponds to the excitationof localized surface plasmon resonances. The (±1,0) Rayleigh anomaliesare indicated by the up-sloping and down-sloping dark lines. The up- anddown-sloping lattice resonances can be observed slightly red-shifted tothe Rayleigh anomalies. The origin of the surface lattice resonances isthe coupling of localized surface plasmons to the aforementionedRayleigh anomalies. It can be observed that the lower (−1,0) latticeresonance disappears near k_(//)=0, giving rise to a frequency gap inthe dispersion diagram of the antenna array. Advantageously, such afrequency gap allows for forming a distributed feedback laser 500.

FIG. 6B shows the extinction of the array at a small angle of incidence(˜1.2 degrees) as the length of the antenna (in the x direction)decreases while all other parameters (antenna width, height, latticeconstants, etc.) are kept constant. The extinction spectrum is limitedto the frequencies where the surface lattice resonances, such asdescribed in FIG. 6A, occur for the given angle of incidence. Theobserved peaks in extinction correspond to the excitation of surfacelattice resonances, and the dips in extinction near 7.07 mrad/nm and 7.2mrad/nm correspond to the (1,0) and (−1,0) Rayleigh anomalies,respectively. The extinction shown in FIG. 6A corresponds to an antennaof length 450 nm; for this length, the (−1,0) surface lattice resonanceis not present at such small angles of incidence, i.e. there is a singleresonance. As the antenna length decreases, however, the extinctionspectrum changes from having a single resonant peak to two resonantpeaks, as shown in FIG. 6B. Particularly interesting is the region near250 nm antenna length, where a dip (the electromagnetically inducedtransparency region) can be observed between the two peaks. Thefrequency at which, in this configuration, this dip in extinction occursis equal to the frequency of the (−1,0) Rayleigh anomaly. The antennaarray may, however, be designed such that the electromagnetic inducedtransparency occurs at other Rayleigh anomalies, such as the (0,−1), the(−1,1), or the (2,1) Rayleigh anomaly.

Thus in an embodiment, the antenna array 530 is arranged such that itsupports surface lattice resonances near the secondary wavelength light522 emitted from the illumination device 500 and a Rayleigh anomalycrosses a surface lattice resonance at a frequency corresponding to thesecondary wavelength light. Such a configuration can be arranged byappropriately designing the antenna geometrical form factor (L×W×H)relative to the periodicities of the array.

While the above is described in conjunction with an array displaying aninduced transparency near 7 mrad/nm (corresponding to a wavelength of˜888 nm), appropriate adjustment of the array parameters allowsdesigning the transparency anywhere in the visible spectrum. Forinstance, an array of silver antennas with dimensions 250×70×20 nm³configured in a rectangular lattice with constants a_(x)=350 nm anda_(y)=200 nm, will yield a localized plasmon resonance for the shortaxis of the antennas at λ=483 nm, and results in a surface latticeresonance near λ=587 nm. Moreover, reducing the width of the antennasfrom 70 nm to 40 nm will shift the localized plasmon resonance furtherinto the blue; while reducing the lattice constant a_(x)=350 nm to saya_(x)=250 nm, blue-shifts the surface lattice resonances to near 450 nm.

Beneficially the electromagnetically induced transparency allowsfabricating a distributed feedback surface polariton lighting device500, such as depicted in FIG. 5. Such a device may further comprise anoptional cavity 560 embedding or straddling the wavelength conversionmedium 520 and the antenna array 530. The cavity 560 is formed bymirrors 561 and 562. Mirror 561 is transparent to the primary wavelengthlight 511 while being reflective for the secondary wavelength light 522.Mirror 562 is at least partially reflective for the secondary wavelengthlight. Advantageously, the emission of the wavelength conversion medium520 in close proximity of the antenna array 530 will be enhanced, sincethe coupling to the resonant antennas increases the decay rate for theemitters in the wavelength conversion medium. Despite this emissionenhancement, the antenna array 530 remains transparent to far fieldextinction at the emission frequency of the wavelength conversion medium520 due to the electromagnetically induced transparency. The possibilityof simultaneous emission enhancement and far-field transparency arisesfrom the different near-field and far-field behavior of the antennaarray 530. Thus, this allows the lighting device 500 to function notonly as a (super-fluorescent) LED, but also as a laser. Alternatively, adistributed feedback laser may also be created with an antenna array 530having a dispersion such as that shown in FIG. 6A, i.e. without anelectromagnetically induced transparency. In such a device, lasing ispossible at the band edges, i.e. near the frequency gap where the twosurface lattice resonances approach each other in frequency. The mainadvantage of having an electromagnetically induced transparency at thesecondary wavelength resides in the possibility of embedding the antennaarray 530 in a cavity 560 such as depicted in FIG. 5, while havingsimultaneous resonant enhancement of the emission and negligible lossesof the feedback light within the cavity. It is important to realize thatwithout this induced transparency, any secondary wavelength light thatis being recycled within the cavity is likely to be absorbed orscattered by the antenna array 530, since the antennas are resonant atthe secondary wavelength 522.

In yet another embodiment, the illumination device comprises a waveguidestructure as depicted in FIG. 7A positioned in light receivingrelationship with its light source. The waveguide structure comprises awavelength converting medium 720 arranged in close proximity of anantenna array 730 and clad by a transparent substrate 740 and atransparent medium 760. Transparent substrate 740 (f.i. SiO₂−n=1.46) andtransparent medium 760 (f.i. air−n=1) have an index of refraction lowerthan the index of refraction of the wavelength converting medium 720(f.i. YAG:Ce−n=1.7) to induce guided modes for light in the latter. Theantenna array 730 is immersed in a coating 750 (such as Si₃N₄−n=2.0)arranged to enhance the optical uniformity of the environmentsurrounding the array, allowing a more efficient coupling of primaryand/or secondary wavelength light the waveguide modes in the wavelengthconverting medium 720 with the localized surface plasmon resonances atthe antenna's and the surface lattice resonances in the antenna array730. A strong coupling between the localized surface plasmon resonancesand the waveguide modes leads to a polaritonic hybrid mode that ischaracterized by relative long life times and large quality factors,thus allowing enhancing and tailoring the light emitted by theillumination device.

The antenna array 730 in the waveguide structure allows for coupling thefar field incident primary light of the illumination device's lightsource into the guided modes of the waveguide 720, which are otherwiseinaccessible by far-field illumination due to momentum mismatch. Thewavelength converting medium 720 typically has a thickness between 50nm-5 μm, more preferably between 100 nm-1 μm, even more preferablybetween 200 nm-800 nm. The coating 750 surrounding the antennas has athickness between 5 nm-50 nm, preferably between 10 nm-40 nm, such as 20nm. It may be applied by first depositing a layer of f.i. Si₃N₄ on thewavelength converting medium 720, followed by positioning the antennaarray using substrate conformal imprint lithography, and finished off bya second layer of f.i. Si₃N₄ encapsulating the antennas through plasmaenhanced chemical vapor deposition. As an additional advantage thecoating 750 protects the antenna array against the detrimentalconsequences of oxidation.

FIG. 7B shows the extinction of light through the waveguide structure ofFIG. 7A. One can observe three distinct features. First of all,independent of the angle of incidence, between about 500-550 nm thelocalized surface plasmon resonances at the individual antennas can beidentified. Furthermore, two resonance structures can be identified. Thefirst at about 760 nm for a 0° angle of incidence can be attributed tothe Rayleigh anomalies and surface lattice resonances described above inconjunction with FIGS. 5&6. The second resonance structure at about 700nm for a 0° angle of incidence can be associated with the polaritonichybrid modes of the strongly coupled waveguide modes and the localizedsurface plasmon resonances. The spectral and angular position of theresonance structures, both in extinction and in emission (not shown) maybe tuned in dependence of the size, shape, and material of the antennas,the periodicity of the antenna array, the presence and thickness of thewaveguide and coating, and the refractive index of the transparentsubstrate 740 and medium 760. This allows a versatile design of theapplication specific illumination distribution provided by theillumination device. For instance, omitting the coating 750 around theantennas 730 induces too large optical inhomogeneities for the surfacelattice resonances to occur. Alternatively, increasing the index ofrefraction of substrate 740 and material 760 to the index of refractionof the wavelength converting material 720 or above will prevent thewaveguide modes to occur.

Thus, proposed is an illumination device designed to provide anapplication specific illumination distribution, comprising: (i) a lightsource arranged to emit light at a primary wavelength, (ii) a waveguidestructure comprising a wavelength conversion medium arranged in lightreceiving relationship with the light source and designed to convert atleast part of the primary wavelength light into secondary wavelengthlight, and a periodic antenna array disposed in close proximity to thewavelength conversion medium and arranged such that the antenna arraysupports coupling of localized surface plasmon resonances in individualantennas with the wave guide modes for enabling the application specificillumination distribution. In an embodiment the antenna array isencapsulated with a coating for increasing the optical homogeneity ofthe antenna environment for supporting surface lattice resonancesarising from diffractive coupling of localized surface plasmonresonances in individual antennas.

Although the invention has been elucidated with reference to theembodiments described above, it will be evident that alternativeembodiments may be used to achieve the same objective. The scope of theinvention is therefore not limited to the embodiments described above.Accordingly, the spirit and scope of the invention is to be limited onlyby the claims and their equivalents.

1. A device comprising: a light source, for generating light sourcelight; and a luminescent material, for converting at least part of thelight source light into luminescent material light, wherein theluminescent material comprises hexagonal phase(K_(1-r-l-n-c-nh)Rb_(r)Li_(l)N_(n)Cs_(c)(NH₄)_(nh))₂Si_(1-m-t-g-s-zr)Mn_(m)Ti_(t)Ge_(g)Sn_(s)Zr_(zr)(F_(1-cl-b-i)Cl_(cl)Br_(b)I_(i))₆,wherein m is in the range of 0.001-0.15, wherein t, g, s, and zr areeach individually in the range of 0-0.2, with t+g+s+zr is greater than 0and equal to or smaller than 0.2, wherein r is in the range of 0.2-0.8,wherein 1, n, c, and nh are each individually in the range of 0-0.2,with l+n+c+nh greater than 0 and equal to or smaller than 0.2, whereincl, b, and i are each individually in the range of 0-0.2, with cl+b+igreater than 0 and equal to or smaller than 0.2; wherein the luminescentmaterial is in direct contact with the light source.
 2. The device ofclaim 1 further comprising a transmissive dome disposed over theluminescent material.
 3. The device of claim 1, further comprising atransmissive coating disposed over the luminescent material.
 4. Thedevice of claim 3, wherein the transmissive coating is selected from thegroup consisting of a polymeric layer, a silicone layer, an epoxy layer,silicon dioxide, and silicon nitride.
 5. The device of claim 1 whereinthe luminescent material further comprises M₃A₅O₁₂:Ce³⁺, wherein M isselected from the group consisting of Sc, Y, Tb, Gd, and Lu, and whereinA is selected from the group consisting of Al and Ga.
 6. The device ofclaim 1 wherein the luminescent material further comprises M₂Si₅N₈:Eu²⁺,wherein M is selected from the group consisting of Ca, Sr, and Ba. 7.The device of claim 1 wherein the light source light comprises UV light,the luminescent material further comprising BaMgAl₁₀O₁₇:Eu²⁺.
 8. Thedevice of claim 1 wherein a combination of the light source light andthe luminescent material light has a correlated color temperaturebetween 2000 and 20000K.
 9. The device of claim 1 wherein a combinationof the light source light and the luminescent material light is within15 standard deviation of color matching from the black body locus.
 10. Adevice comprising: a light source, for generating light source light;and a luminescent material, for converting at least part of the lightsource light into luminescent material light, wherein the luminescentmaterial comprises hexagonal phase(K_(1-r-l-n-c-nh)Rb_(r)Li_(l)Na_(n)Cs_(c)(NH₄)_(nh))₂Si_(1-m-t-g-s-zr)Mn_(m)Ti_(t)Ge_(g)Sn_(s)Zr_(zr)(F_(1-cl-b-i)Cl_(cl)Br_(b)I_(i))₆,wherein m is in the range of 0.001-0.15, wherein t, g, s, and zr areeach individually in the range of 0-0.2, with t+g+s+zr is greater than 0and equal to or smaller than 0.2, wherein r is in the range of 0.2-0.8,wherein 1, n, c, and nh are each individually in the range of 0-0.2,with l+n+c+nh greater than 0 and equal to or smaller than 0.2, whereincl, b, and i are each individually in the range of 0-0.2, with cl+b+igreater than 0 and equal to or smaller than 0.2; wherein the luminescentmaterial is spaced apart from the light source.
 11. The device of claim10 wherein the light source is disposed in a chamber with reflectivewalls.
 12. The device of claim 10 wherein the luminescent material isdisposed on a transparent window.
 13. The device of claim 10 wherein theluminescent material is disposed on both sides of a transparent window.14. The device of claim 10 wherein the luminescent material is spacedbetween 0.1 mm and 10 cm from the light source.
 15. The device of claim10 wherein the luminescent material further comprises M₃A₅O₁₂:Ce³⁺,wherein M is selected from the group consisting of Sc, Y, Tb, Gd, andLu, and wherein A is selected from the group consisting of Al and Ga.16. The device of claim 10 wherein the luminescent material furthercomprises M₂Si₅N₈:Eu²⁺, wherein M is selected from the group consistingof Ca, Sr, and Ba.
 17. The device of claim 10 wherein the light sourcelight comprises UV light, the luminescent material further comprisingBaMgAl₁₀O₁₇:Eu²⁺.
 18. The device of claim 10 wherein a combination ofthe light source light and the luminescent material light has acorrelated color temperature between 2000 and 20000K.
 19. The device ofclaim 10 wherein a combination of the light source light and theluminescent material light is within 15 standard deviation of colormatching from the black body locus.
 20. A device comprising: a lightsource, for generating light source light; and a luminescent material,for converting at least part of the light source light into luminescentmaterial light; wherein the light source comprises a light emittingdiode (LED); wherein the luminescent material comprises a phosphorcomprising M₂AX₆ doped with tetravalent manganese, wherein M comprisesmonovalent cations, at least comprising potassium and rubidium, whereinA comprises a tetravalent cation, at least comprising silicon, wherein Xcomprises a monovalent anion, at least comprising fluorine, whereinM₂AX₆ has the hexagonal phase, and wherein M₂AX₆ has a luminous efficacygreater than 200 lm/W; and wherein the luminescent material is spacedapart from the light source.